How does melting absorb heat at a constant temperature?
When a pure crystalline solid reaches its melting point, it undergoes a phase change from solid to liquid. During this process, the temperature remains constant because the energy being added is not used to increase the kinetic energy of the particlesāwhich would raise the temperatureābut is instead absorbed as latent heat, specifically the heat of fusion.123
This absorbed energy is required to perform the work necessary to overcome the attractive forces holding the atoms or molecules in their stable, ordered crystalline lattice positions. By providing this energy, the substance transitions into a more disordered liquid state where particles are free to move, even though they remain cohesive. Once the entire mass of the solid has melted, any additional heat applied will then contribute to increasing the temperature of the resulting liquid.23