How is titanium sponge formed during the Kroll process?
In the Kroll process, titanium sponge is formed by reducing titanium tetrachloride () with magnesium (Mg) metal.1
This chemical reaction occurs within large, sealed steel vessels at temperatures ranging from approximately 800 to 1,000 °C (1,450 to 1,800 °F). To prevent contamination from air or moisture, the process is conducted in an inert argon atmosphere. The resulting product is a highly porous material known as sponge, which contains magnesium chloride () salts trapped within its pores.1
Following the reaction, the sponge is crushed, and the metal is separated from the salts through either a dilute acid leach or high-temperature vacuum distillation. The recovered salts are then recycled through electrolytic cells to regenerate magnesium and chlorine for further use in the production cycle.1