How is magnesium used in the Kroll process for making titanium?
In the Kroll process, magnesium serves as the reducing agent used to extract metallic titanium from titanium tetrachloride ().12
The process is conducted in a sealed steel vessel under an inert argon atmosphere to prevent contamination from air or moisture. The reaction occurs at approximately 800 to 1,000 °C, where molten magnesium reacts with to produce metallic titanium in the form of a highly porous material known as "sponge".12
Following the reaction, the resulting mixture contains the titanium sponge along with entrapped magnesium chloride () and excess magnesium. These impurities are subsequently removed through either a dilute acid leach or high-temperature vacuum distillation. The magnesium chloride byproduct is often recycled through electrolytic cells to recover magnesium for reuse in the reduction process.12