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Step-growth polymerization is a chemical process where polymers are formed by the stepwise combination of monomer molecules that contain reactive functional groups. Unlike chain-growth polymerization, which adds monomers to a growing chain, step-growth polymerization builds molecular weight gradually through random reactions between monomers.12345

Common examples of step-growth polymers include polyesters, epoxies, and polyurethanes, often formed by reactions between different types of monomers, such as acids and alcohols. These reactions can sometimes produce by-products like water, leading them to be called condensation reactions.34

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