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principal quantum number

chemistry and physics

Quick Summary

The principal quantum number, denoted by n, is a fundamental concept in chemistry and physics that describes the energy level of an electron within an atom. It is an integer that begins with 1 and increases as the electron's energy and average distance from the nucleus grow.123

  • Energy Level: A higher principal quantum number signifies a higher energy state for the electron.12
  • Distance from Nucleus: As n increases, the electron is likely to be found farther from the nucleus.13
  • Shells: All orbitals with the same principal quantum number n constitute an electron shell. The n=1 shell is closest to the nucleus and has the lowest energy, while higher n values represent shells farther away and with higher energy.23

The principal quantum number is one of several quantum numbers used to uniquely identify an electron's state within an atom.12

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