oxidative fluorination

chemical reaction

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June 11, 2026

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Oxidative fluorination is a chemical reaction where fluorine, the most reactive element, acts as a powerful oxidizing agent. In such reactions, fluorine atoms attract electrons, leading to an increase in the oxidation state of other elements. This process is a type of oxidation-reduction (redox) reaction.12

Fluorine, a halogen, readily combines with most elements to form fluorides. Due to its extreme reactivity, free fluorine is not found in nature. The strength of fluorine as an oxidizing agent increases from astatine to fluorine itself, making elemental fluorine the most potent. Oxidative fluorination reactions are crucial in various industrial processes, including the production of fluorocarbons used in plastics and refrigerants.23

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krypton
Compounds
Hence, in a formal sense, oxidative fluorination is the net result of extraction of two electrons and addition of F⁻; this can be considered to be equivalent to the transfer of F⁺.) KrF₂ is, for example, capable of oxidizing and fluorinating xenon to XeF₆ and gold to AuF₅.
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Hence, in a formal sense, oxidative fluorination is the net result of extraction of two electrons and addition of F⁻; this can be considered to be equivalent to the transfer of F⁺.) KrF₂ is, for example, capable of oxidizing and fluorinating xenon to XeF₆ and gold to AuF₅.
Read More