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lithium aluminum hydride

chemical compound

Quick Summary

Lithium aluminum hydride (LiAlH₄) is a white, flammable solid that is soluble in ether. It is synthesized by reacting lithium hydride (LiH) with anhydrous aluminum chloride.1

LiAlH₄ is a powerful reducing agent, particularly for organic compounds, capable of converting carboxylic acids into alcohols. It is classified as a complex saline hydride, a type of hydride compound where hydrogen exists as a negatively charged ion (H⁻). These compounds are strong bases and react readily with water, releasing hydrogen gas. Lithium hydride (LiH) itself is a flammable crystalline solid used as a source of hydrogen and in the synthesis of other lithium compounds, including lithium aluminum hydride.123

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