Britannica AI Icon

Quick Summary

An indicator electrode is a type of electrode used in electroanalysis to measure the concentration or activity of a specific chemical species in a solution. It works in conjunction with a reference electrode, which has a constant potential. The potential difference between these two electrodes is measured by a voltmeter, and this difference is directly related to the concentration of the analyte.

There are two main types of indicator electrodes:
* Inert electrodes: These are made of materials like platinum or gold and reflect the potential of the bulk solution.
* Ion-selective electrodes (ISEs): These are designed to respond preferentially to a single chemical species. They use a special membrane that selectively interacts with the analyte. Examples include glass electrodes, commonly used for pH measurements, which respond to hydrogen ions.1

Indicator electrodes are crucial in potentiometry, a common electroanalytical method, and are also used in titrations to detect the endpoint by observing changes in electrical properties.21

Summary created from Britannica articles using AI. AI can make mistakes, so verify using Britannica articles.

Ask Britannica AI about this topic

Britannica doesn't have a full article on this topic, so we've curated a list of our relevant coverage.