Britannica AI Icon

enthalpy of reaction

chemical reaction

Quick Summary

The enthalpy of reaction, represented by (\Delta H), is the heat added or removed during a chemical reaction to maintain a constant temperature. If the pressure remains constant, this heat change is equivalent to the change in enthalpy, which is the difference between the enthalpy of the products and reactants.12

A reaction is endothermic if (\Delta H) is positive, meaning heat is absorbed. Conversely, a reaction is exothermic if (\Delta H) is negative, indicating heat is released. Breaking chemical bonds requires energy, while forming them releases energy. The net energy change determines whether a reaction is endothermic or exothermic.13

Hess's law states that the total enthalpy change for a chemical reaction is constant, regardless of the steps involved. This principle allows for the calculation of reaction enthalpies using known data, such as heats of formation.41

Summary created from Britannica articles using AI. AI can make mistakes, so verify using Britannica articles.

Ask Britannica AI about this topic

Britannica doesn't have a full article on this topic, so we've curated a list of our relevant coverage.