Britannica AI Icon

Quick Summary

A buffer solution in chemistry is a solution that resists changes in hydrogen ion concentration. It typically contains a weak acid and its conjugate base, or vice versa.

The chemical equation that describes the hydrogen ion concentration in a buffer solution is often represented by the Henderson-Hasselbalch equation:

[ \text{pH} = \text{p}K_a + \log_{10}\left(\frac{[\text{A}^-]}{[\text{HA}]}\right) ]

Here, pH is the measure of acidity, pKa is the acid dissociation constant, [A-] is the concentration of the base, and [HA] is the concentration of the acid. The ratio of the concentrations of the base to the acid, [A-]/[HA], is known as the buffer ratio. This ratio is crucial because it determines the buffer's capacity to resist pH changes when acids or bases are added. Maintaining a specific buffer ratio is essential for many chemical and biological experiments where stable pH levels are required.123

Summary created from Britannica articles using AI. AI can make mistakes, so verify using Britannica articles.

Ask Britannica AI about this topic

Britannica doesn't have a full article on this topic, so we've curated a list of our relevant coverage.