Britannica AI Icon

Quick Summary

In chemistry, an amorphous polymer is a type of polymer where the molecules are randomly oriented and intertwined, similar to cooked spaghetti. This random arrangement gives amorphous polymers a glass-like, transparent appearance.1

Unlike semicrystalline polymers, which have ordered regions called crystallites, amorphous polymers lack this structure. This lack of order means they tend to be less tough than semicrystalline polymers, which benefit from strong intermolecular forces due to close chain packing.1

Amorphous polymers, like other amorphous solids, exhibit a glass transition temperature (Tg). Below this temperature, they are in a rigid, glassy state. Above Tg, they enter a rubbery state with increased molecular motion, allowing them to be molded or shaped. Examples of common amorphous polymers include polystyrene and polyvinyl chloride.123

Summary created from Britannica articles using AI. AI can make mistakes, so verify using Britannica articles.

Ask Britannica AI about this topic

Britannica doesn't have a full article on this topic, so we've curated a list of our relevant coverage.