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addition polymerization

chemical reaction
Also known as: chain-growth polymerization

Quick Summary

Addition polymerization is a chemical reaction where monomers, which are small molecules, chemically combine to form a very large molecule called a polymer. Unlike condensation polymerization, this process occurs without the formation of by-products. Catalysts are often used in addition polymerization, and they can influence the final properties of the polymer.12

Common examples of addition polymers include polyethylene, polypropylene, polystyrene, and polyvinyl chloride. These materials are often thermoplastic, meaning they can be softened by heating. The formation of stable covalent chemical bonds between monomers distinguishes polymerization from other aggregation processes.341

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