Why can one chlorine atom help produce many chloromethane molecules?

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The production of many chloromethane molecules from a single chlorine atom is possible because the process is a chain reaction.12

In this mechanism, the chlorine atom acts as a transient intermediate that is consumed in one step but regenerated in another, allowing it to facilitate multiple reaction cycles. The process follows these propagation steps:1

  • A chlorine atom (·Cl) reacts with a methane molecule (CH4) to produce a methyl radical (·CH3) and hydrogen chloride (HCl).2
  • The resulting methyl radical then reacts with a chlorine molecule (Cl2) to form the product, chloromethane (CH3Cl), and a new chlorine atom (·Cl).2

Because the chlorine atom is regenerated in the second step, it is free to collide with another methane molecule and repeat the cycle. This sequence continues until a termination step occurs—such as the combination of two radicals—which breaks the chain. This efficient regeneration is why a single act of initiation can result in the production of many molecules of the final product.123