Britannica Sources used in this answer

How does ultraviolet radiation cause CFCs to release chlorine atoms?

Created from Britannica articles using AI. AI can make mistakes, so verify using Britannica articles.

When chlorofluorocarbons (CFCs) reach the stratosphere, they are exposed to high-energy ultraviolet radiation from the Sun. This radiation causes the CFC molecules to undergo a process called dissociation, in which the chemical bonds holding the molecule together are broken.12

This breakdown releases highly reactive chlorine atoms and free radicals. Once liberated, these chlorine atoms act as catalysts that strip oxygen atoms from ozone molecules, effectively destroying them and contributing to the depletion of the ozone layer.12