How does stretching strengthen natural rubber?

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Natural rubber, which consists primarily of the cis-1,4 polyisoprene polymer, is considered a self-reinforcing material because of its unique behavior when subjected to mechanical force.1

Under normal conditions, the long-chain molecules of natural rubber exist in an irregularly coiled, disordered state. When the material is stretched, these polymer chains straighten out in the direction of the applied force. As they are pulled, the chains readily undergo crystallization. This stress-induced crystallization creates ordered regions within the material, which significantly increases its toughness and strength.21

Because of this ability to crystallize upon stretching, natural rubber can be extended repeatedly to seven or eight times its original length without failing, making it highly resilient for applications such as tires, springs, and mountings.1