How does acetic acid dissociate when dissolved in water?
When acetic acid is dissolved in water, it undergoes dissociation by donating a proton () to a water molecule, which acts as a base. This process is represented by the following equilibrium equation:
CHCOH + HO â CHCO + HO1
In this reaction, the acetic acid molecule loses a proton to become a negatively charged carboxylate ion, specifically an acetate ion (CHCO), while the water molecule gains the proton to form a hydronium ion (HO).12
The extent of this dissociation is governed by the dissociation constant (), which for acetic acid is 1.76 à 10 at 25 °C. Because acetic acid is a weak acid, it does not dissociate completely in water; the degree of dissociation depends on the concentration of the solution, with the fraction of dissociated acid increasing as the concentration decreases.3