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Pierre Gy was a French chemist renowned for his comprehensive theory of sampling, developed in the latter half of the 20th century. He distinguished between two types of material heterogeneity: constitution heterogeneity, relating to the intrinsic properties of a material's components, and distribution heterogeneity, concerning how these components are spatially mixed.1

Gy's work emphasized the importance of ensuring all constituents of a material have an equal probability of being included in a sample. He critiqued "grab sampling" as non-probabilistic and often inadequate for heterogeneous materials, advocating instead for probabilistic sampling methods that offer a chance for all constituents to be sampled. His theories are fundamental to accurately representing larger systems in laboratory samples.1

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