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How does mayonnaise become firm during preparation?

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Mayonnaise becomes firm during preparation through the process of creating an emulsion, which involves the continuous beating of egg yolks while adding vegetable oil gradually.1

The firmness is achieved because the egg yolk acts as an emulsifier, containing substances like lecithins that stabilize the mixture. The emulsifier has a hydrophobic portion that dissolves in the oil and a hydrophilic portion that dissolves in the aqueous phase (such as vinegar or lemon juice), allowing the oil to be suspended as small droplets within the liquid. As more oil is incorporated into this stable suspension through constant agitation, the mixture thickens into a firm, creamy consistency.21