Britannica Sources used in this answer

How did en passant become part of the rules of chess?

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The rule of en passant was introduced to maintain the strategic balance of the game after the pawn was granted the option to move two squares on its initial turn.12

When pawns were restricted to moving only one square at a time, they could not bypass an enemy pawn's reach. By allowing a two-square opening move, the rules created a scenario where a pawn could "skip" over a square controlled by an opponent. En passant—French for "in passing"—was implemented to ensure that a pawn could still be captured as if it had only moved one square, preventing players from using the two-square jump to evade capture.2

Although this rule was known as early as the 15th century, it did not gain widespread acceptance until the 18th century. It remains a unique, situational rule that must be exercised immediately after the opponent's two-square pawn advance, or the right to do so is lost.12