Why were alkaline fuel cells used on U.S. space shuttle orbiters?

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Alkaline fuel cells were utilized on U.S. space shuttle orbiters because they provided a reliable and efficient power source for manned spacecraft.12

While the design of these cells presented significant engineering challenges—specifically because the strong, hot alkaline electrolyte tends to penetrate structural joints and attack many plastics—these issues were successfully overcome to enable their use in space flight. Like other hydrogen-oxygen fuel cells used in earlier missions such as Apollo and Gemini, these systems offered the distinct advantage of producing a vital byproduct: drinkable fresh water. By continuously combining hydrogen and oxygen, these fuel cells were able to deliver an unwavering supply of electricity throughout the mission.13