Britannica
Sources used in this answer
Why does silver tarnish when exposed to sulfur or hydrogen sulfide?
Created from Britannica articles
using AI.
AI can make mistakes, so verify using Britannica articles.
Silver tarnishes when exposed to sulfur or hydrogen sulfide because it reacts with these substances to form a layer of silver sulfide () on its surface.1
While silver is highly valued for its resistance to atmospheric oxidationâmeaning it does not react with dry oxygen or moist airâit is chemically reactive toward sulfur-containing compounds. When silver comes into contact with sulfur or hydrogen sulfide at room temperature, a chemical reaction occurs that creates this dark, dull tarnish. This process is a notable exception to silver's general stability, as it is one of the "noblest" or least reactive transition elements.12