Why do toughened ceramics lose some of their advantages at high temperatures?

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Toughened ceramics often lose their mechanical advantages at elevated temperatures due to the degradation of the specific mechanisms that provide their toughness. The reasons for this loss vary by the type of toughening method employed:1

  • Transformation-toughened ceramics: In materials like transformation-toughened zirconia, toughness relies on a stress-induced phase transformation. As the temperature rises, the driving force for this phase change decreases and eventually disappears, causing the material to lose its toughening effect.1
  • Reinforced composites: In ceramics reinforced with whiskers or fibres, these components are frequently susceptible to high-temperature oxidation. When oxidation occurs, these agents are effectively eliminated, causing the ceramic matrix to revert to its inherent, brittle behavior.1

Because these toughening mechanisms are not inherently stable at high heat, a primary challenge for engineers is developing microstructures that maintain their integrity and toughness in such demanding environments.1