Which polymers are used to make thermosetting adhesives?

Created from Britannica articles using AI. AI can make mistakes, so verify using Britannica articles.

Thermosetting adhesives are characterized by their ability to form permanent, heat-resistant, and insoluble bonds through a curing process that creates a cross-linked network. Unlike thermoplastics, these materials cannot be softened or reshaped by heating once they have cured.1

The primary polymers used to make thermosetting adhesives include:

  • Epoxies: Widely used for their high strength and excellent resistance to heat and solvents.23
  • Phenol-formaldehyde resins: Frequently utilized in structural wood products, such as plywood, due to their strong bonding capabilities and moisture resistance.41
  • Urea-formaldehyde: Another common thermosetting resin used in adhesive applications.1
  • Polyurethanes: Known for their flexibility and resistance to shock and fatigue.21
  • Unsaturated polyesters: Used in various thermosetting adhesive systems.1

Additionally, elastomer-based adhesives can function as thermosets if they undergo a cross-linking process during their application. These polymers are essential in demanding fields such as the aerospace industry where structural integrity under stress is required.1