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What happens when molybdenum trioxide sublimates during roasting?
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When molybdenum trioxide () sublimates, it vaporizes directly from the solid state into a gas.1
In the context of roasting molybdenite concentrate, this process is generally avoided because the temperature in the furnace should not exceed 650 °C (1,200 °F), which is the point at which sublimation occurs.1
However, sublimation is intentionally utilized in a separate refining stage to produce chemically pure . During this process, technical-grade oxide is heated in electric retorts to temperatures between 1,200 and 1,250 °C (2,200 and 2,300 °F). The resulting sublimed vapors are swept from the furnace tubes by air and collected in filter bags to separate pure from volatile impurities.2