How is pure electrolytic manganese produced?

Created from Britannica articles using AI. AI can make mistakes, so verify using Britannica articles.

To produce pure electrolytic manganese, manganese ores are first roasted to create an MnO calcine, which is then dissolved in sulfuric acid to produce a manganous sulfate solution.1

The purification process involves:
* Precipitation: Ammonia is added to remove iron and aluminum, while hydrogen sulfide is used to precipitate other impurities, including arsenic, copper, zinc, lead, cobalt, and molybdenum.1
* Electrolysis: The purified solution is fed into the cathode portion of an electrolytic cell. When an electric current is applied, manganese is deposited onto a stainless-steel cathode sheet.1
* Finishing: The resulting manganese layers are removed from the cathodes by hammering. These flakes are then heated to 500 °C (925 °F) to eliminate hydrogen, yielding a final product with a purity greater than 99.9 percent.1