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How is ferrovanadium produced in an electric-arc furnace?

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The production of ferrovanadium, which typically contains 35–80 percent vanadium, is carried out in an electric-arc furnace. The process involves the following steps:

  • Melting: Scrap iron is first melted in the furnace.
  • Charging: A mixture of vanadium pentoxide (V2O5), aluminum, and a flux—such as calcium oxide or calcium fluoride—is added to the molten iron.
  • Reaction: An exothermic oxidation-reduction reaction occurs where the aluminum reduces the V2O5 to vanadium metal, which then dissolves into the molten iron. The aluminum is converted into alumina, forming a slag.
  • Heating: Because the reaction is exothermic, the furnace only needs to reach a kindling temperature of 950° C (1,750° F). Once the reaction is kindled, the electrodes are withdrawn until the process is complete.
  • Refining: Finally, the electrodes are reinserted into the molten slag to reheat the furnace, which improves the settling of the alloy.1