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How does liquation separate tin from impurities with higher melting points?
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In the context of tin processing, liquation is a fire refining method used to separate tin from impurities that possess a higher melting point than the metal itself.12
The process is carried out using a reverberatory furnace equipped with a sloping hearth. The impure tin or dross is placed on this hearth and heated to a temperature maintained just above the melting point of tin. Because the tin has a lower melting temperature than the associated impurities, it melts and flows down the slope, where it is collected in a separate vessel. The unmelted residues, containing the higher-melting-point impurities, remain on the hearth to be removed and treated subsequently.2