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Why is sulfuric acid stronger than sulfurous acid?
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oxyacid
The structure of phosphorous acid, H3PO3.
The strength of an oxyacid is determined by the extent to which it dissociates in water to form hydrogen ions. For a given nonmetal central atom, acid strength increases as the oxidation number of that central atom increases.1
In the case of sulfur-based oxyacids, sulfuric acid () is a stronger acid than sulfurous acid () because the sulfur atom in sulfuric acid is in a +6 oxidation state, whereas the sulfur atom in sulfurous acid is in a +4 oxidation state. This higher oxidation state in sulfuric acid contributes to its greater ability to donate protons in solution.1