Why does acid react with chalk to produce carbon dioxide bubbles?

Created from Britannica articles using AI. AI can make mistakes, so verify using Britannica articles.

Chalk is primarily composed of calcium carbonate (CaCO3), a base that reacts with acids in a gas-forming reaction.

When an acid (such as hydrochloric acid) is applied to chalk, the two substances undergo a chemical process that produces a metal salt, water, and carbon dioxide gas. The reaction can be represented by the following equation:12

CaCO3(s)+2HCl(aq)→CaCl2(aq)+CO2(g)+H2O(l)

The characteristic bubbles, or effervescence, occur because the reaction initially forms carbonic acid (H2CO3), which is unstable and spontaneously breaks down to release carbon dioxide gas. This gas-forming property has historically been used as a simple test to identify calcite and other carbonate-bearing minerals in the field.34