Why does a larger temperature difference increase the maximum efficiency of a Carnot engine?

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The maximum efficiency of a Carnot engine is determined by the temperatures of the heat reservoirs between which it operates. Specifically, the efficiency (η) is given by the relationship η=1−T2/T1, where T1 is the temperature of the hot reservoir and T2 is the temperature of the cold reservoir.12

A larger temperature difference increases efficiency because it allows the engine to minimize the amount of waste heat (Q2) that must be exhausted to the environment. According to the second law of thermodynamics, a heat engine cannot convert all absorbed heat (Q1) into work because the net entropy change of the system must be greater than or equal to zero (ΔS≥0).312

To maximize work (W=Q1−Q2), one must minimize Q2 relative to Q1. The theoretical limit occurs when ΔS=0, which requires Q2/T2=Q1/T1. Consequently, as the ratio T2/T1 decreases—achieved by increasing the temperature difference—the fraction of heat that must be discarded as waste decreases, thereby increasing the maximum possible efficiency.12