Why does a larger temperature difference increase the maximum efficiency of a Carnot engine?
The maximum efficiency of a Carnot engine is determined by the temperatures of the heat reservoirs between which it operates. Specifically, the efficiency () is given by the relationship , where is the temperature of the hot reservoir and is the temperature of the cold reservoir.12
A larger temperature difference increases efficiency because it allows the engine to minimize the amount of waste heat () that must be exhausted to the environment. According to the second law of thermodynamics, a heat engine cannot convert all absorbed heat () into work because the net entropy change of the system must be greater than or equal to zero ().312
To maximize work (), one must minimize relative to . The theoretical limit occurs when , which requires . Consequently, as the ratio decreases—achieved by increasing the temperature difference—the fraction of heat that must be discarded as waste decreases, thereby increasing the maximum possible efficiency.12