Why do saline hydrides release hydrogen gas when mixed with water?

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Saline (or ionic) hydrides release hydrogen gas when mixed with water because they contain the hydride anion (H−), which acts as a strong base.1

When these compounds come into contact with water, the hydride ion reacts instantly and quantitatively with the hydrogen ion (H+) provided by the water molecules. This chemical reaction is represented by the following equation:

H−+H2O→H2+OH−

In this process, the hydride ion accepts a proton from the water, resulting in the formation of hydrogen gas (H2) and the hydroxide ion (OH−) in the solution. Because this reaction is vigorous and produces large volumes of hydrogen, saline hydrides are frequently utilized as portable sources of hydrogen gas.1