Why do polymers have much larger molecular weights than water molecules?

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Polymers have significantly larger molecular weights than water because they are macromolecules—essentially "giant molecules"—formed by the chemical aggregation of many smaller units called monomers.12

While a single water molecule consists of only three atoms (one oxygen and two hydrogen) with a molecular weight of 18 atomic mass units, a polymer is constructed by linking together hundreds or even thousands of monomer units through stable covalent chemical bonds. This process, known as polymerization, results in long, chainlike or network structures that can reach molecular weights ranging from tens of thousands to several million atomic mass units.342

It is this vast size that distinguishes polymers from simpler substances and provides them with their unique physical properties, such as high tensile strength, elasticity, and the ability to be molded into plastics or drawn into fibres.42