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Why do lighter gas molecules move faster than heavier molecules at the same temperature?
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According to the kinetic theory of gases, the temperature of a gas is directly related to the average kinetic energy of its molecules. This relationship is expressed by the formula:
In this equation, represents the mass of the molecule, is its velocity, is the Boltzmann constant, and is the absolute temperature.1
Because the average kinetic energy depends only on the temperature, it remains constant for all gases at the same temperature. Consequently, if the mass () of a gas molecule is smaller, its velocity () must be higher to maintain the same average kinetic energy. This principle explains why lighter gas molecules move faster than heavier ones under identical thermal conditions.1