Why do iron meteorites often develop a black crust during atmospheric entry?

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When iron meteorites pass through Earth's atmosphere, they develop a thin, black crust primarily due to the formation of iron oxide on their surface.1

This feature is a specific type of fusion crust, which is created when the intense heat generated by atmospheric friction causes the surface of the meteorite to melt. While this crust is initially black, it is chemically reactive and will quickly weather to rust after the object reaches the ground.21