Why do hydrogen phosphate salts make basic solutions?

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Aqueous solutions of hydrogen phosphate salts are basic because the hydrogen phosphate ion (HPO42−) acts more effectively as a base—defined as a proton acceptor—than as an acid in water.1

While orthophosphoric acid is a triprotic acid capable of donating three protons, its salts exhibit varying acidity or alkalinity depending on their specific ion composition. Specifically, the HPO42− ion has a greater tendency to accept a proton than to donate one, which results in a basic solution. In contrast, dihydrogen phosphate salts (H2PO4−) form weakly acidic solutions because the ion functions as a weak acid, while orthophosphate salts (PO43−) form strongly basic solutions because the orthophosphate ion is a moderately strong base.1