Why do dihydrogen phosphate salts make weakly acidic solutions?

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Dihydrogen phosphate salts make weakly acidic solutions because they contain the dihydrogen phosphate ion (H2PO4−), which acts as a weak acid in aqueous solution.1

Orthophosphoric acid is a triprotic acid, meaning it can donate three protons in succession. When these salts dissolve in water, the H2PO4− ion is capable of donating a proton, resulting in an acidic environment. In contrast, other phosphate salts behave differently based on their specific ion composition: hydrogen phosphate ions (HPO42−) act as bases because they are stronger proton acceptors than proton donors, while orthophosphate ions (PO43−) are moderately strong bases that produce strongly basic solutions.1