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Why do dihydrogen phosphate salts make weakly acidic solutions?
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oxyacid
The structure of phosphorous acid, H3PO3.
Dihydrogen phosphate salts make weakly acidic solutions because they contain the dihydrogen phosphate ion (), which acts as a weak acid in aqueous solution.1
Orthophosphoric acid is a triprotic acid, meaning it can donate three protons in succession. When these salts dissolve in water, the ion is capable of donating a proton, resulting in an acidic environment. In contrast, other phosphate salts behave differently based on their specific ion composition: hydrogen phosphate ions () act as bases because they are stronger proton acceptors than proton donors, while orthophosphate ions () are moderately strong bases that produce strongly basic solutions.1