Britannica
Sources used in this answer
Why did silicon replace germanium in many semiconductor devices?
Created from Britannica articles
using AI.
AI can make mistakes, so verify using Britannica articles.
silicon
Chemical properties of the element silicon.
Silicon replaced germanium as the primary material for semiconductor devices for several key reasons:
- Thermal Stability: Silicon devices can operate at significantly higher temperatures than those made of germanium. While germanium diodes are limited to approximately 85 °C (185 °F), silicon diodes can function at temperatures up to 200 °C (400 °F).1
- Leakage Currents: Devices fabricated from silicon exhibit much lower leakage currents than their germanium counterparts, making them more suitable for a wider range of applications.2
- Insulating Properties: Unlike germanium, silicon forms a high-quality, tenaciously adhering oxide film (silicon dioxide) when heated in the presence of oxygen. This film serves as an excellent electrical insulator and a critical mask during the photolithographic manufacturing process, enabling the creation of complex integrated circuits.21
- Abundance and Cost: Silicon is much more abundant in the Earth's crust than germanium, which makes it a more cost-effective raw material for large-scale manufacturing.1
These advantages allowed silicon technology to become the industry standard, currently accounting for more than 95 percent of all semiconductor products sold worldwide.2