Why can polar water molecules pull ions out of some materials?
Water molecules are able to pull ions out of solid materials because they are polar, meaning they possess a permanent electric dipole due to their angular shape and the unequal distribution of electrical charge across their atoms.12
In a water molecule, the oxygen atom carries a partial negative charge, while the hydrogen atoms carry a partial positive charge. When an ionic solid is placed in water, these partial charges interact with the ions in the crystal lattice. The positive ends of the water molecules are attracted to the anions, and the negative ends are attracted to the cations.123
This process, known as hydration, allows water to surround and stabilize the individual ions. By replacing the strong forces between the ions in the solid with strong water-ion interactions, water effectively minimizes the energy difference required for the crystal to dissolve, causing the solid to break apart into separate, hydrated ions.31