Why can phosphoric acid form three different series of phosphate salts?

Created from Britannica articles using AI. AI can make mistakes, so verify using Britannica articles.

Phosphoric acid (also known as orthophosphoric acid, H3PO4) can form three different series of phosphate salts because it is a triprotic acid. This means that in an aqueous solution, the molecule is capable of donating all three of its hydrogen atoms as protons.1

The three series of salts correspond to the replacement of one, two, or three of these hydrogen atoms:2

  • Dihydrogen phosphates: Contain the H2PO4− ion, formed by the replacement of one hydrogen atom.1
  • Hydrogen phosphates: Contain the HPO42− ion, formed by the replacement of two hydrogen atoms.1
  • Orthophosphates: Contain the PO43− ion, formed by the replacement of all three hydrogen atoms.1

Because each step of this deprotonation process involves different chemical properties, these salts exhibit varying levels of acidity or basicity when dissolved in water.1