Why can concentrated or heated ether peroxides be dangerous?
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Ethers can be dangerous because they undergo a process called autoxidation, which is the spontaneous reaction of the compound with oxygen in the air. This process leads to the formation of hydroperoxides and dialkyl peroxides. These resulting peroxides are highly unstable and may explode if they become concentrated or are heated.1
To ensure safety and prevent such hazardous explosions, it is essential to follow proper handling protocols:
* Obtain ethers in small quantities.
* Keep them stored in tightly sealed containers.
* Use the chemicals promptly.1