Britannica
Sources used in this answer
Why are thiocarbonyl compounds often deeply colored and highly reactive?
Created from Britannica articles
using AI.
AI can make mistakes, so verify using Britannica articles.
organosulfur compound
Examples of organosulfur compounds.
Thiocarbonyl compounds, which contain the thiocarbonyl group (), are often deeply colored and highly reactive due to the nature of the double bond between carbon and sulfur.1
This reactivity and color arise because the bond involves orbitals of significantly different sizes: the 2 orbital of carbon and the 3 orbital of sulfur. Because these orbitals do not overlap well, the resulting bond is weaker and more reactive than the corresponding carbon-oxygen double bond, which utilizes similar 2 orbitals for both atoms.12
The poor orbital overlap and the resulting electronic structure are responsible for the distinct physical and chemical properties of these compounds compared to their oxygen-containing counterparts.2