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Why are mercury(II) compounds more common than mercury(I) compounds?
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mercury
Properties of mercury.
Mercury compounds exist in both +1 and +2 oxidation states, but mercury(II) (mercuric) compounds are more common than mercury(I) (mercurous) compounds.1
While mercury can lose two electrons to form dipositive ions (), the mercury(I) ion () is diatomic, meaning it requires two mercury atoms to share electrons in a covalent bond. The ion is more versatile in its chemical behavior, as it readily forms complex ions and covalent bonds, whereas the ion shows little tendency to form such complexes. Furthermore, mercury(II) compounds are central to a wide variety of industrial, medical, and agricultural applications, including their use as catalysts and pigments.123