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Why are alkali-metal atoms relatively large?

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Alkali-metal atoms are relatively large because they possess only a single, weakly bound electron located in a large outer s-type orbital.1

As you move through the periodic table, the addition of an electron to an alkali metal atom results in that electron occupying a larger orbital—such as the 4s orbital for potassium—rather than a smaller, inner orbital. This configuration, characterized by a single valence electron that is not strongly held, contributes to the overall large atomic size and the resulting low density of these metals.1