Why are +2 oxidation states more stable for tin and lead than for carbon and silicon?
The tendency for elements in the carbon group to favor the +2 oxidation state over the +4 state increases as the atomic number increases.
While carbon and silicon are very stable in the +4 state, the heavier elements in the family exhibit a growing inertness of the electron pair. These electrons are closer to the nucleus than the electrons and become increasingly difficult to remove as the atomic number rises. This phenomenon, often referred to as the inert pair effect, allows the electrons to be removed separately, facilitating the formation of +2 ions in elements like tin and lead.
Consequently, while carbon and silicon do not form stable +2 ions, tin shows roughly equal stability in both +2 and +4 states, and lead is dominated by the +2 oxidation state, with only weak tetrapositive properties.12