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Which electronic state is the ground state of methylene?
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carbene
Nonbonding orbitals in triplet and singlet states
The ground state of methylene () is the triplet state.1
In this state, the two nonbonding electrons occupy different orbitals and have parallel spins, which results in a magnetic moment. Experimental evidence from magnetic resonance spectroscopy confirms this configuration, showing a bond angle of 136°. While methylene can exist in a singlet state—where electrons are paired in the same orbital—this form is higher in energy and has a smaller bond angle of 104°. Generally, carbenes with only carbon or hydrogen substituents, such as methylene, are characterized by a triplet ground state.1