Which aldehydes are gases or liquids under ordinary conditions?

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Under ordinary conditions, the physical state of an aldehyde is primarily determined by its molecular weight.

  • Gases: Formaldehyde (HCHO), the simplest aldehyde, exists as a gas under standard conditions.1
  • Liquids: Acetaldehyde (CH₃CHO) boils at approximately room temperature. Most other aldehydes are liquids under ordinary conditions, provided they do not have a high molecular weight.1

The polarity of the carbonyl group results in higher boiling points for aldehydes compared to nonpolar hydrocarbons of similar molecular weight, as the polar molecules require more energy to separate.1