What happens to arsenic vapor molecules as their temperature increases?

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In its vapor state, arsenic exists as As4 molecules. As the temperature of this vapor increases, the following changes occur:

  • Dissociation begins: The As4 molecules remain stable until the temperature reaches approximately 800 °C, at which point they begin to dissociate.1
  • Complete dissociation: As the temperature continues to rise, the dissociation process progresses until it is complete at about 1,700 °C, at which point the vapor consists of As2 molecules.1