What discovery by Neil Bartlett showed that xenon could form compounds?

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In 1962, British chemist Neil Bartlett discovered that platinum hexafluoride (PtF6) could remove an electron from molecular oxygen to form the salt [O2+][PtF6−].1

Recognizing that the first ionization energy of xenon is very similar to that of oxygen, Bartlett hypothesized that xenon could be oxidized in a similar fashion. He subsequently demonstrated that the interaction of PtF6 vapor with xenon gas at room temperature produced a yellow-orange solid compound, which he formulated as [Xe+][PtF6−]. This landmark achievement proved that noble gases—previously considered chemically inert—could indeed form chemical compounds.12