Under which conditions do real gases behave most like ideal gases?

Real gases behave most like ideal gases under conditions of high temperature and low pressure.123

In these states, the molecules of a gas are separated by relatively large distances, and their high speeds allow them to overcome intermolecular forces. Under such conditions, the ideal gas law—which assumes that gas molecules have negligible volume and do not interact with one another except during elastic collisions—provides a very close approximation of the gas's physical behavior.324

Conversely, real gases deviate from ideal behavior when they are at high densities or near their condensation point, where intermolecular forces and the finite volume of the molecules become significant.123