Britannica
Sources used in this answer
How is potassium metal commercially produced from potassium chloride?
Created from Britannica articles
using AI.
AI can make mistakes, so verify using Britannica articles.
potassium
Properties of potassium.
Potassium metal is not produced through electrolysis because there are few salt additives capable of lowering the melting point of potassium chloride to a range where electrolytic processes are efficient.1
Instead, commercial production is achieved through the sodium reduction of molten potassium chloride at 870 °C (1,600 °F). In this process, molten potassium chloride is continuously fed into a packed distillation column while sodium vapour is passed upward through it. The reaction is represented by the following equation:1
By condensing the more volatile potassium at the top of the distillation tower, the reaction is effectively forced to the right, allowing for the recovery of the metal.1